Search results for "optical [potential]"
showing 10 items of 5737 documents
The S … Hal and Se … Hal chalcogen bonding in a series of thiourea, selenourea and their derivatives
2021
The chalcogen bonding (ChB) in a series of thiourea, selenourea and their derivatives has been investigated in the present paper. Thus, selenourea and dimethylselenourea undergo dimerization and trimerization processes in the presence of various halogen species (1–5). Selenourea and dimethylselenourea form trimers 3–4 in the presence of lighter halogens (chlorine and bromine) through Se⋯Se chalcogen bonding. When moving to heavier halogen (iodine), the dimers 1–2 are formed. Thiourea and its derivatives also tend to make very strong S⋯S bonds and form dimers in the case of lighter halogens chlorine and bromine (compounds 6–7). However, the monomers separated by the iodine species are formed…
Tetracyclic silaheterocycle formed through a pericyclic reaction cascade including a two-fold intramolecular C–C bond activation
2022
Reductive debromination of the tribromoamidosilane 2 gave the tetracyclic silaheterocycle 3 through a unique reaction cascade involving unprecedented two-fold intramolecular cycloaddition by transient silylenes. Experimental and computational analyses of the reaction mechanism allowed the identification of the key intermediates that lead to the silaheterocycle 3 or, alternatively, to the cyclotrisilene 19. peerReviewed
Reply to : “Topological and trivial domain wall states in engineered atomic chains”
2022
publishedVersion Non peer reviewed
Flat bands, Dirac cones, and atom dynamics in an optical lattice
2010
We study atoms trapped with a harmonic confinement in an optical lattice characterized by a flat band and Dirac cones. We show that such an optical lattice can be constructed which can be accurately described with the tight binding or Hubbard models. In the case of fermions the release of the harmonic confinement removes fast atoms occupying the Dirac cones while those occupying the flat band remain immobile. Using exact diagonalization and dynamics we demonstrate that a similar strong occupation of the flat band does not happen in bosonic case and furthermore that the mean field model is not capable for describing the dynamics of the boson cloud.
Quantum effects in one-dimensional optical flat-band lattices
2011
I numerically simulated one-dimensional lattice systems describable by the Hubbard-model and containing a flat-band. I studied the manner in which particles initially held in place by a parabolic confinement potential are dispersed across the lattice after the potential is removed. I also studied currents flowing within one-dimensional Hubbard-rings. In both of these cases I observed that the flat dispersion relation of the flat-band manifests itself as the immobility of the particles occupying it. Particles occupying flat-band states do not disperse even after the removal of any external confinement, neither do they contribute to a current within a ring.
A delay model valid in all the regions of operation of the MOS transistor for the energy-efficient design of MCML gates
2013
This paper presents a novel delay model for MCML circuits valid in all the regions of operation of the MOS transistor, i.e., weak inversion (sub-threshold), moderate inversion (near-threshold) and strong inversion. The proposed delay model was employed to develop an automated methodology for the energy-efficient design of such circuits. The tradeoff that can be realized between energy and delay was investigated. Experiments were performed using different technologies to understand the impact of technology scaling on that tradeoff too. Major results of this study are as follows. In a circuit designed for minimum energy consumption, the minimum energy point occurs in the near-threshold region…
All-Organic Waveguide Sensor for Volatile Solvent Sensing
2019
This work was supported by ERDF 1.1.1.1 Activity Project Nr. 1.1.1.1/16/A/046 “Application assessment of novel organic materials by prototyping of photonic devices”. We acknowledge Igors MIHAILOVS for valuable discussions.
Op art et roman virtuel : correspondances entre Escher et Perec
2012
Op art et roman virtuel : correspondances entre Escher et Perec Les structures mathématiques, la notion de réalité comme « humaine illusion », le défi à l’infini et la structure énigmatique qui donne aux œuvres eschériennes la même structure que celle d’un roman policier permettent d’établir des convergences significatives entre le graveur hollandais et Georges Perec. Dans certaines œuvres de Perec, en effet, il est possible de remarquer des références explicites au graveur bien qu’elles constituent la traduction visuelle de l’angoisse du « retour du semblable », du « retour involontaire au même point ». Mais Perec ne se limite pas seulement à citer Escher, puisque certaines de ses œuvres c…
Electrochemical Oxidation of Hf-Nb Alloys as a Valuable Route to Prepare Mixed Oxides of Tailored Dielectric Properties
2018
Metal oxides with high dielectric constant are extensively studied in the frame of substituting SiO2 as gate dielectric in nanoelectronic devices. Here, high-k mixed HfO2/Nb2O5 oxides are prepared by a facile electrochemical route starting from sputtering-deposited Hf–Nb alloys with several compositions. Transmission electron microscopy, grazing incidence X-ray diffraction, and glow discharge optical emission spectroscopy are employed to study the oxide structures, disclosing a crystalline–amorphous transition of the electrochemically prepared oxides by increasing the Nb content. Photo-electrochemical measurements allow the observation of optical transitions ascribed to localized states ins…
Purcell Enhancement and Wavelength Shift of Emitted Light by CsPbI3 Perovskite Nanocrystals Coupled to Hyperbolic Metamaterials
2020
Manipulation of the exciton emission rate in nanocrystals of lead halide perovskites (LHPs) was demonstrated by means of coupling of excitons with a hyperbolic metamaterial (HMM) consisting of alternating thin metal (Ag) and dielectric (LiF) layers. Such a coupling is found to induce an increase of the exciton radiative recombination rate by more than a factor of three due to the Purcell effect when the distance between the quantum emitter and HMM is nominally as small as 10 nm, which coincides well with the results of our theoretical analysis. Besides, an effect of the coupling-induced long wavelength shift of the exciton emission spectrum is detected and modeled. These results can be of i…